An Easy Way to Print Envelopes in MS Word Printing envelopes can be pretty easy in MS Word. I imagine that you would find this tip useful when you don’t have your addresses typed into MS Word /Address Book or when you are just creating single envelopes (for mass mailing, it is advisable to use mail merge – this would be discussed in my future posts). Printing addresses on envelopes gives that professional touch to your work and ensures that you don’t waste your ‘limited’ time writing delivery addresses. Here’s how to print Envelopes in MS Word. I assume that MS Word is already opened. Step 1: Go to Tools on the main menu > Letters and Mailing > Envelopes…